Q: Does the electron in an atom make a jump from one
orbit to the other without traveling in between? Is that description
according to Bohr's theory correct?
A:
Firstly, I would like to outline the Bohr theory: it's pretty much a
model of an atom imagining it to be like the solar system. Indeed, both
the Coulomb force and the Gravity force have inverse square dependence.
But the difference is in the energies involved: energy is quantised in units of h, the Plank constant (since
this fact was discovered by Plank in 1900), which is a very small
quantity. Since the solar system is very large, h does now play a very
important role there. However, atoms are very small, and so we cannot
go very far treating atoms exactly like the solar system.
There is one more difference, which was a great difficulty
for the Rutherford (solar-system) model of the atom: electron are
moving charges rotating around the nucleus, and a rotating (or in any
sense accelerating) charge emits light continuously, thus losing energy
(which the light carries away). The electron would collapse into the
nucleus. Also, we don't see a continuous emission of light from atoms.
And the light which IS emitted is of some very particular frequencies... so particular that we can recognize an element from it's "signature" of frequencies emitted.
What Bohr did was reconcile Plank's hypothesis with
Rutherford's theory... he said that electrons only move in certain
orbits around the nucleus, and even though they still rotate, they
don't emit light. They do so only when they change orbits... go from
one nearer the nucleus to one further away. That changes the energy of
the electron (one nearer the nucleus has less energy), and this
difference in energy is emitted. Since the orbits and their energies
are different for different elements, the emitted light has different
energies, and thus different elements have different "spectra", or
"signatures".
The Bohr theory was puzzling in some respects: why don't
electrons emit light even though they rotate? Why are only certain
orbits allowed? Can an electron be in the space between the orbit while
it is jumping from one to the other? (Some of our textbooks answered
this with a confident "no". I don't think Bohr said so, he just said
the transitions cannot be treated according to classical laws.)
The "real" theory of the atom is the quantum mechanical
theory, based on Schroedinger's equation. If you have read a little
about QM, you know that all particles are treated as "waves". That is a
vague way of putting it: these "waves" are in fact probability waves, which means that where a wave is strong, or
have a high (crest), the particle is more likely to be found there. We
cannot state where exactly the particle is: we can only give the
probabilities for it to be found at the place where we are doing the
measuring.
A better description of QM in this context (Atoms) might be in the concept of "states". For example, if I measure the energy of a particle which I put in a box, it will only have certain values
. Energy is almost always discretised, since (for the physics
students among us), the Schroedinger equation is essentially an
eigenvalue equation for the energy. (Forget that if you didn't get it.)
Anyway, energy, in most situations, has only discrete values, which
means measuring it will only give me one of the values from that set,
and no other. For example, I will only get 0,1,2,3,4,5... (appropriate
units), but not 1.5,2.3333..., 3.14159... . I may get 1 90% of the time
and 0 10% of the time, but I will never get 0.9 . This means that the
particle can only be found (ie, measured to be) in certain "states".
For
example, on a flight of stairs, a person may be on the 2nd stair, or
the 5th stair, but he cannot be standing in between two stairs. He may
be on the 1st stair 40% of the time, on the 2nd 10% of the time, on the
third 5% of the time and so on. Which means I can only find him in
certain "states", which I may label state one (1st stair), state two
(2nd stair) and so on.
The quantum mechanical solution of the (hydrogen) atom says
that the particle can only be found in certain states (these are the
Bohr orbits: it can be in the first, nearest, orbit, the second one, or
so on...). However, remember this is QM: the electron does not "rotate" around the nucleus. In fact, it
has a some probability of being found anywhere in the atom, and the
probability is maximum at a certain distance (which can be taken as the
"radius" of it's orbit). But what it does have fixed is not the
position of the orbit, but it's energy: so different orbits correspond to the different energy states. In the first state, it has a certain energy, in the second, it has another energy, etc.
An electron also can, under some conditions, be in a superposition of two states.
It being in a single state means that it will always be measured to
have the same energy. A superposition means that it can be measured to
have two different energies, with some probability for each. Eg., a
superposition of the "first step" and "third step" means that the
person can be found for sometimes on the 1st step, and sometimes on the
2nd step, with certain probability.
A superposition of states under an oscillating external field results in
an oscillation term in the the probability... ie, the electron
may, at a certain time, have 100% probability of being found with one
energy, and a certain time later, have 100% probability of being found
with the other energy. That is, when a light of a certain frequency is
incident on the atom, the electron state is changed due to the light
wave, and the electron is now in a superposition of two states with
different energies. So, at a certain time, it has 100% probability of
being found in an upper energy state. This means that the electron has
absorbed energy from the incident light. Since the electron's energy is
increased by a certain amount, that means it has absorbed a "photon" of
that energy from the light.
Now, for any frequency of light incident on the electron, it
is thrown into a superposition of many, many energy levels (states).
But, the superposition is "strong" only if the light has an energy equal to the difference between two of the energy levels
. This means that the electron will most probably transition to that upper state which satisfies this condition. (A "strong" superposition means that the electron transition probability is appreciable
.) This is why light of a certain frequency will only cause certain
transitions. This is responsible for the "spectrum" of the electron...
ie, the absorption and emission of light of certain frequencies by a
particular element.
A visual picture can be painted if we imagine the electron
as an "electron cloud" (which is what it is, after all... a single
electron actually can be imagined to be a fuzzy cloud, with high
probability of being found where the cloud is denser, and low
probability where it is lighter). In the stationary states inside the
atom, the electron has different "cloud shapes", if you will, in
different states. Each cloud is densest at a certain distance from the
nucleus, which we can call the "radius" of the state. Under an external
oscillating field, the cloud changes shape, and becomes one stationary
type of shape for some time, a "middle", superposed state for some
time, and then another stationary shape for some time. Thus, the radius
changes, energy is absorbed or emitted, etc. (Note that a normal
superposed state has a different cloud shape than either of the two
superposing stationary states.)
Thus, the textbooks are wrong, the "radius" does change
continuously when the electron is making a transition... the radius
doesn't radically change.